Life and work
Gustav Kirchhoff was born in Königsberg, East Prussia, the son of Friedrich Kirchhoff, a lawyer, and Johanna Henriette Wittke. He graduated from the Albertus University of Königsberg in 1847 where he attended the mathematico-physical seminar directed by Franz Ernst Neumann and Friedrich Julius Richelot. He married Clara Richelot, the daughter of his mathematics professor Richelot. In the same year, they moved to Berlin, where he stayed until he received a professorship at Breslau.
Kirchhoff formulated his circuit laws, which are now ubiquitous in electrical engineering, in 1845, while still a student. He completed this study as a seminar exercise; it later became his doctoral dissertation. In 1857 he calculated that an electric signal in a resistanceless wire travels along the wire at the speed of light.[1] He proposed his law of thermal radiation in 1859, and gave a proof in 1861. He was called to the University of Heidelberg in 1854, where he collaborated in spectroscopic work with Robert Bunsen. Together Kirchhoff and Bunsen discovered caesium and rubidium in 1861. At Heidelberg he ran a mathematico-physical seminar, modelled on Neumann's, with the mathematician Leo Koenigsberger. Among those who attended this seminar were Arthur Schuster and Sofia Kovalevskaya. In 1875 Kirchhoff accepted the first chair specifically dedicated to theoretical physics at Berlin.
In 1862 he was awarded the Rumford Medal for his researches on the fixed lines of the solar spectrum, and on the inversion of the bright lines in the spectra of artificial light.
He contributed greatly to the field of spectroscopy by formalizing three laws that describe the spectral composition of light emitted by incandescent objects, building substantially on the discoveries of David Alter and Anders Jonas Angstrom (see also: spectrum analysis).
He also contributed to optics, carefully solving Maxwell's equations to provide a solid foundation for Huygen's principle (and correcting it in the process).[2]
Kirchhoff died in 1887, and was buried in the St Matthäus Kirchhof Cemetery in Schöneberg, Berlin.[3]
Kirchhoff's three laws of spectroscopy
1. A hot solid object produces light with a continuous spectrum.
2. A hot tenuous gas produces light with spectral lines at discrete wavelengths (i.e. specific colors) which depend on the energy levels of the atoms in the gas. (See also: emission spectrum)
3. A hot solid object surrounded by a cool tenuous gas (i.e. cooler than the hot object) produces light with an almost continuous spectrum which has gaps at discrete wavelengths depending on the energy levels of the atoms in the gas. (See also: absorption spectrum)
Kirchhoff did not know about the existence of energy levels in atoms. The existence of discrete spectral lines was later explained by the Bohr model of the atom, which helped lead to quantum mechanics.
Kirchhoff's law of thermochemistry
Kirchhoff showed in 1858 that the variation of the heat of a chemical reaction is given by the difference in heat capacity between products and reactants: dΔH / dT = ΔCp. Integration of this equation permits the evaluation of the heat of reaction at one temperature from measurements at another temperature
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